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Chapter 17 - Electric potential

17.1Overview

In this chapter, we develop the concept of electric potential energy and electric potential. This will allow us to describe the motion of charges using energy instead of forces. We will also introduce the capacitor, a common circuit component that is used to store charge.

17.2Electric potential energy

Mathematically, Coulomb’s Law for the electric force is identical to Newton’s Universal Theory of Gravity for the gravitational force. The electric force is thus conservative, and the work done by the electric force on a charge, qq, when the charge moves from position AA in space to some other position BB, cannot depend on the path taken. Since the work done by the electric force only depends on the location of the initial (AA) and final (BB) positions, we can define an electrical potential energy function, U(r)U(\vec r), that depends on position, r\vec r. The work done by the electric force, FE\vec F^E, on a charge in going from position AA (defined by position vector, rA\vec r_A), to position BB (defined by position vector, rB\vec r_B), can be written as:

W=ABFEdr=ΔU=[U(rB)U(rA)]W=\int_A^B \vec F^E\cdot d\vec r=-\Delta U=-\left[ U(\vec r_B)-U(\vec r_A) \right]

In order to determine the function, U(r)U(\vec r), we can choose a path over which the integral for work is easy to calculate. Consider a point charge, +Q+Q, that exerts an electric force on another charge, +q+q, as in Figure 1. We will calculate work done by the electric force as it moves +q+q from a distance rAr_A to a distance rBr_B from the centre of +Q+Q.

Calculating the work done on a charge $+q$ by the electric force exerted by charge $+Q$ when charge $+q$ moves from a distance $r_A$ to a distance $r_B$ from the centre of charge $+Q$.

Figure 1:Calculating the work done on a charge +q+q by the electric force exerted by charge +Q+Q when charge +q+q moves from a distance rAr_A to a distance rBr_B from the centre of charge +Q+Q.

Placing +Q+Q at the origin of a coordinate system, the force exerted on +q+q, when it is located at position r\vec r, is given by:

FE=kQqr2r^\vec F^E=k\frac{Qq}{r^2}\hat r

The work done by the electric force when +q+q moves from rAr_A to rBr_B is given by:

W=ABFEdr=rArB(kQqr2r^)dr=kQqrArB1r2dr=kQq[1r]rArB=(kQqrBkQqrA)\begin{align*} W&=\int_A^B \vec F^E\cdot d\vec r=\int_{\vec r_A}^{\vec r_B} \left(k\frac{Qq}{r^2}\hat r\right)\cdot d\vec r=kQq \int_{r_A}^{r_B} \frac{1}{r^2}dr\\ &=kQq \left[\frac{-1}{r} \right]_{r_A}^{r_B}=-\left(\frac{kQq}{r_B}-\frac{kQq}{r_A}\right) \end{align*}

where we noted that, since FE\vec F^E and drd\vec r are parallel, their scalar product is simply the product of their magnitudes. By comparing with (1), we can identify the potential energy, U(r)U(\vec r), of a charge, +q+q, located at a relative position, r\vec r, from a point charge, +Q+Q, as:

U(r)=kQqr+C\boxed{U(\vec r)=\frac{kQq}{r}+C}

where the potential energy is only defined up to some constant, CC, which cancels when we take the difference in potential energy between two positions. Note that this is very similar to the function for the gravitational potential energy of a mass, mm, a distance, rr, from a mass, MM (see Section 9.4).

The potential energy function that we derived above remains the same if one or both of the charges change sign. The only difference in the derivation would be that the direction of the force, FE\vec F^E, could change. For example, a positive charge, +q+q, near a negative charge, Q-Q, would have negative electric potential energy with the choice C=0C=0, in exact analogy with gravity.

17.2.1Electrostatic potential energy

When we hold two positive charges together a distance, rr, apart, we need to exert a force on the charges in order to keep the charges in place (as they repel each other). If we release the charges, they will move apart from each other until all of the stored electric potential energy is converted into kinetic energy. The energy that was originally stored in this “system” of two charges is called “electrostatic potential energy”. In this section, we show how to model the energy stored in a collection of point charges.

Consider a single positive charge, q1q_1, located at the origin of empty space. Since there are no other charges present, it does not “cost” us any energy to place that charge there - we do not need to do any work. If we now bring in a second positive charge, q2q_2, and place it a distance, r12r_{12}, from q1q_1 (Figure 2), we will need to do work since q1q_1 exerts a force on q2q_2. We define zero potential energy to be at infinity, which means choosing C=0C=0 for electric potential energy. The work, Wq2W_{q2}, that we must do on q2q_2 to bring it from infinity to a distance, r12r_{12}, from q1q_1 is given by the corresponding change in potential energy of q2q_2:

Wq2=ΔU=UfinalUinitial=kq1q2r120=kq1q2r12W_{q2}=\Delta U=U_{final}-U_{initial}=k\frac{q_1q_2}{r_{12}}-0=k\frac{q_1q_2}{r_{12}}

Note that the work is done by us (not by the electric field), so it has the same sign as the change in potential energy (we must do positive work to increase potential energy). The work that we did corresponds to the same amount of electrostatic potential energy stored in this arrangement of two charges (the only source of that stored electrostatic potential energy is the work that we did on the charge q2q_2).

Three positive charges arranged together will store a certain amount of electrostatic potential energy.

Figure 2:Three positive charges arranged together will store a certain amount of electrostatic potential energy.

Now, we bring in a third positive charge, q3q_3, also from infinitely far away, as illustrated in Figure 2. In order to bring in q3q_3, we need to do work against the forces exerted by both q1q_1 and q2q_2. Suppose that we place q3q_3 a distance r13r_{13} from q1q_1 and r23r_{23} from q2q_2. Then, the amount of work done by us to bring in q3q_3 is given by:

Wq3=kq1q3r13+kq2q3r23W_{q3}=k\frac{q_1q_3}{r_{13}}+k\frac{q_2q_3}{r_{23}}

and the total electrostatic energy stored in the system of three charges is given by the sum of the work done to place q2q_2 and the work done to place q1q_1:

E=Wq1+Wq2+Wq3=0+kq1q2r12+kq1q3r13+kq2q3r23E = W_{q1}+W_{q2}+W_{q3}=0+k\frac{q_1q_2}{r_{12}}+k\frac{q_1q_3}{r_{13}}+k\frac{q_2q_3}{r_{23}}

If we have any number of charges (positive and negative), we can always calculate the stored electrostatic energy by proceeding in a similar fashion.

17.3Electric potential

As you recall, we defined the electric field, E(r)\vec E(\vec r), to be the electric force per unit charge. By defining an electric field everywhere in space, we were able to easily determine the force on any test charge, qq, whether the test charge is positive or negative (since the sign of qq will change the direction of the force vector, qEq\vec E):

E(r)=FE(r)qFE(r)=qE(r)\begin{align*} \vec E(\vec r) &= \frac{\vec F^E(\vec r)}{q}\\ \therefore \vec F^E(\vec r)&=q\vec E(\vec r) \end{align*}

Similarly, we define the electric potential, V(r)V(\vec r), to be the electric potential energy per unit charge. This allows us to define electric potential, V(r)V(\vec r), everywhere in space, and then determine the potential energy of a specific charge, qq, by simply multiplying qq with the electric potential at that position in space.

V(r)=U(r)qU(r)=qV(r)\begin{align*} V(\vec r) &= \frac{ U(\vec r)}{q}\\ \therefore U(\vec r)&= q V(\vec r) \end{align*}

The S.I. unit for electric potential is the “volt” (V). Electric potential, V(r)V(\vec r), is a scalar field whose value is “the electric potential” at that position in space. Say that the electric potential at a position in space is V=10VV=10 {\rm V}. The above formula tells us that a positive charge q=1Cq=1 {\rm C}, located at that position, will have a potential energy of U=10JU=10 {\rm J}. Similarly, a negative charge, q=1Cq=-1 {\rm C}, will have negative potential energy, U=10JU=-10 {\rm J}, at the same location.

Since only differences in potential energy are physically meaningful, only changes in electrical potential are physically meaningful. A difference in electric potential is commonly called a “voltage”. One often makes a clear choice of where the electric potential is zero (typically the ground, or infinitely far away), so that the term voltage is used to describe potential, VV, instead of difference in potential, ΔV\Delta V; this should only be done when it is clear where the location of zero electric potential is defined.

We can describe a free-falling mass by stating that the mass moves from a region where it has high gravitational potential energy to a region of lower gravitational potential energy under the influence of gravity (the force associated with a potential energy always acts in the direction to decreases potential energy). The same is true for electrical potential energy: charges will always experience a force in a direction to decrease their electrical potential energy. However, positive charges will experience a force driving them from regions of high electric potential to regions of low electric potential, whereas negative charges will experience a force driving them from regions of low electric potential to regions of higher electric potential. This is because, for negative charges, the change in potential energy associated with moving through space, ΔU\Delta U, will be the negative of the corresponding change in electric potential, ΔU=qΔV\Delta U=q\Delta V, since the charge, qq, is negative.

If the only force exerted on a particle is the electric force, and the particle moves in space such that the electric potential changes by ΔV\Delta V, we can use conservation of energy to determine the corresponding change in kinetic energy of the particle:

ΔE=ΔU+ΔK=0ΔU=qΔV\begin{align*} \Delta E &= \Delta U + \Delta K = 0\\ \Delta U &= q\Delta V\\ \end{align*}
ΔK=qΔV\boxed{\therefore \Delta K = -q \Delta V}

where ΔE\Delta E is the change in total mechanical energy of the particle, which is zero when energy is conserved. The kinetic energy of a positive particle increases if the particle moves from a region of high potential to a region of low potential (as ΔV\Delta V would be negative and qq is positive), and vice versa for a negative particle. This makes sense, since a positive and negative particle feel forces in opposite directions.

In order to describe the energies of particles such as electrons, it is convenient to use a different unit of energy than the Joule, so that the quantities involved are not orders of magnitude smaller than 1. A common choice is the “electron volt”, eV}. One electron volt corresponds to the energy acquired by a particle with a charge of ee (the charge of the electron) when it is accelerated by a potential difference of 1V1 {\rm V}:

ΔE=qΔV1eV=(e)(1V)=1.6×1019J\begin{align*} \Delta E &= q\Delta V\\ 1 {\rm eV}&=(e)(1 {\rm V})=1.6\times 10^{-19} {\rm J} \end{align*}

An electron that has accelerated from rest across a region with a 150V150 {\rm V} potential difference across it will have a kinetic of 150eV=2.4×1017J150 {\rm eV}=2.4\times 10^{-17} {\rm J}. As you can see, it is easier to describe the energy of an electron in electron volts than Joules.

17.3.1Electric potential from electric field

At the beginning of Section 17.2, we determined the potential energy of a point charge, qq, in the presence of another point charge, QQ (Figure 1). This was done by calculating the work done by the Coulomb (electric) force exerted by charge QQ on qq. We can write the same integral for the work done by the electric force on qq, but using the electric field, E\vec E, to write the force:

W=ABFEdr=ABqEdr=qABEdr\begin{align*} W&=\int_A^B \vec F^E\cdot d\vec r=\int_A^B q \vec E\cdot d\vec r=q \int_A^B \vec E\cdot d\vec r \end{align*}

where we recognized that the charge, qq, is constant and can come out of the integral. The integral that is left is thus the work done by the electric field, E\vec E, per unit charge. In other words, this is the negative change in electric potential:

W=qABEdr=qΔV=q[V(rB)V(rA)]W=q \int_A^B \vec E\cdot d\vec r=-q\Delta V = -q\left[ V(\vec r_B)-V(\vec r_A) \right]
ΔV=V(rB)V(rA)=ABEdr\boxed{\therefore \Delta V =V(\vec r_B)-V(\vec r_A)=-\int_A^B \vec E\cdot d\vec r}

which allows us to easily determine the change in electric potential associated with an electric field. Note that this result is general and does not require the electric field to be that of a point charge, and can be used to determine the electric potential associated with any electric field. We can also specify a function for the potential, up to an arbitrary constant, CC, (think definite versus indefinite integrals):

V(r)=Edr+CV(\vec r)=-\int \vec E\cdot d\vec r + C

The relation between electric potential and electric field is analogous to the relation between electric potential energy and electric force:

ΔV=V(rB)V(rA)=ABEdrΔU=U(rB)U(rA)=ABFEdr\begin{align*} \Delta V &=V(\vec r_B)-V(\vec r_A)=-\int_A^B \vec E\cdot d\vec r\\ \Delta U &=U(\vec r_B)-U(\vec r_A)=-\int_A^B \vec F^E\cdot d\vec r \end{align*}

as the bottom equation is just qq times the first equation. We can think of electric potential being to potential energy what electric field is to electric force. Electric potential and electric field are electric potential energy and electric force, per unit charge, respectively.

For a point charge, QQ, located at the origin, the electric field at some position, r\vec r, is given by Coulomb’s Law:

E=kQr2r^\vec E=\frac{kQ}{r^2}\hat r

The potential difference between location AA (at position rA\vec r_A) and location BB (at position rB\vec r_B), as in Figure 1, is given by:

ΔV=ABEdr=rArBkQr2r^dr=(kQrBkQrA)\begin{align*} \Delta V &=- \int_A^B \vec E\cdot d\vec r= -\int_{\vec r_A}^{\vec r_B} \frac{kQ}{r^2}\hat r\cdot d\vec r=-\left(\frac{kQ}{r_B}-\frac{kQ}{r_A}\right) \end{align*}

and we note that we can write a function for the electric potential, V(r)V(\vec r), at a distance rr from a point charge, QQ, as:

V(r)=kQr+CV(\vec r)=\frac{kQ}{r}+C

where CC is an arbitrary constant. This, of course, is identical to the result that we obtained earlier, for the potential energy of a charge, qq, a distance, rr, from QQ:

U(r)=qV(r)=kQqr+CU(\vec r)=qV(\vec r)=\frac{kQq}{r}+C'

where the constant, C=qCC'=qC, does not have any physical impact. Often, as is the case for gravity, one chooses the constant C=0C=0. This choice corresponds to defining potential energy to be zero at infinity. Equivalently, this corresponds to choosing infinity to be at an electric potential of 0V0 {\rm V}.

17.3.2Electric field from electric potential

In the previous section, we found that we could determine the electric potential (a scalar) from the electric field vector. In this section, we show how to do the reverse, and determine the electric field vector from the electric potential. Consider, first, a one-dimensional case, where the electric field, E(x)=E(x)x^\vec E(x)= E(x) \hat x, point in the xx direction and depends on position, xx. In this one-dimensional case, the electric potential is obtained from the negative anti-derivative of the electric field:

V(x)=E(x)dx=E(x)dxV(x)=-\int \vec E(x)\cdot d\vec x=-\int E(x) dx

The electric field must then be given by the negative of the derivative of the electric potential function:

E(x)=dV(x)dxx^\vec E(x) = -\frac{dV(x)}{dx}\hat x

Note that we can tell from the above that the electric field must have dimensions of electric potential over distance. The most common S.I. unit used to describe the electric field is V/m{\rm V/m} (Volts per meter).

This result is very similar to that obtained in Section 8.3.1, where we examined how one could use the scalar potential energy, U(x,y,z)U(x,y,z), to determine the vector for the force associated with that potential energy. The same holds for the electric force, where we can determine the electric force vector, F\vec F, from the electric potential energy, and similarly the electric field from the electric potential. In three dimensions, if we know the electric potential energy as a function of position, U(r)=U(x,y,z)U(\vec r)=U(x,y,z), then the electric force vector is given by:

F(x,y,z)=U=Uxx^Uyy^Uzz^\vec F(x,y,z) =- \nabla U=-\frac{\partial U}{\partial x}\hat x-\frac{\partial U}{\partial y}\hat y-\frac{\partial U}{\partial z}\hat z

Similarly, but using force per unit charge (i.e. electric field) and potential energy per unit charge (i.e. electric potential), we find:

E(x,y,z)=V=Vxx^Vyy^Vzz^\vec E(x,y,z) = -\nabla V =-\frac{\partial V}{\partial x}\hat x-\frac{\partial V}{\partial y}\hat y-\frac{\partial V}{\partial z}\hat z

where, as you recall, V\nabla V, is called the gradient of the scalar field, V(x,y,z)V(x,y,z). The gradient is a vector that points in the direction of maximal increase of the value of V(x,y,z)V(x,y,z). For a positive charge, this corresponds to the direction of maximal increase in potential energy. A positive charge will experience a force in the opposite direction (in the direction where the potential energy decreases the fastest), and the electric field is thus in the opposite direction from the gradient of the electric potential.

17.3.3Equipotential surfaces

We can visualize electric potential in several ways, since it is a scalar field (it has a single value that can differ everywhere in space). Figure 7 shows the electric potential near a positive charge, +Q+Q, where we have chosen 0V0 {\rm V} to be located at infinity. The right panel shows the electric potential as a “surface plot”, where the vertical direction is the value of the electric potential. The left panel shows a “heat map” of the electric potential, where the colour corresponds to the value of the electric potential.

Electric potential heat map (left) and surface plot (right) near a single positive charge.

Figure 7:Electric potential heat map (left) and surface plot (right) near a single positive charge.

The most common way to visualize the electric potential is to draw “contour lines”, similar to how one draws contour lines on a geographical map. On a geographical map, contours correspond to lines of constant altitude, which are also lines of constant gravitational potential energy. Similarly, we can draw lines of constant electric potential. Lines of constant potential are called “equipotential lines”. In three dimensions, regions of constant electric potential can be surfaces or volumes, called “equipotential surfaces/volumes”.

The electric field vector is always perpendicular to equipotential lines/surfaces. At any point in space, the electric field vector points opposite to the gradient of the electric potential, since E=V\vec E=-\nabla V. This means that the electric field points in the direction where the potential decreases the fastest, which must be perpendicular to the direction where the potential stays the same (i.e. the equipotential lines). Another way to think about this is to consider a charge moving along an equipotential. By definition, the electric potential energy of the charge does not change if its moves along an equipotential. As a result, the electric force/field cannot do any work on the charge, and so must be perpendicular to the path of the charge.

In order to draw equipotential lines, you can start by drawing electric field lines, and then draw (closed) contour lines that are everywhere perpendicular to the electric field lines. This is illustrated in Figure 8.

The electric field and equipotential lines caused by two $+2q$ charges and one $-3q$ charge (left) and its corresponding electric potential heatmap (right).

Figure 8:The electric field and equipotential lines caused by two +2q+2q charges and one 3q-3q charge (left) and its corresponding electric potential heatmap (right).

In general, it is preferable to draw equipotential lines at equal increments of potential (e.g. every 10V10 {\rm V}). For example, the equipotential lines for a point charge located at the origin consist of concentric circles centred at the origin (in three dimensions, this results in concentric spherical equipotential surfaces). If we define 0V0 {\rm V} to be at infinity, the electric potential is given by:

V(r)=kQrV(r)=\frac{kQ}{r}

In order to draw equipotential lines every 10V10 {\rm V}, the radii of the corresponding equipotential circles, for V=10VV=10 {\rm V}, V=20VV=20 {\rm V}, V=30VV=30 {\rm V}, etc., are given by:

r=kQVr10V=kQ(10V)r20V=kQ(20V)r30V=kQ(30V)\begin{align*} r&=\frac{kQ}{V}\\ r_{10V}&=\frac{kQ}{(10 {\rm V})}\quad r_{20V}=\frac{kQ}{(20 {\rm V})}\quad r_{30V}=\frac{kQ}{(30 {\rm V})}\quad \dots \end{align*}

17.4Calculating electric potential from charge distributions

In this section, we give two examples of determining the electric potential for different charge distributions. We have two methods that we can use to calculate the electric potential from a distribution of charges:

  1. Model the charge distribution as the sum of infinitesimal point charges, dqdq, and add together the electric potentials, dVdV, from all charges, dqdq. This requires that one choose 0V0 {\rm V} to be located at infinity, so that the dVdV are all relative to the same point.
  2. Calculate the electric field (either as a integral or from Gauss’ Law), and use:
ΔV=V(rB)V(rA)=ABEdr\begin{align*} \Delta V &=V(\vec r_B)-V(\vec r_A)=-\int_A^B \vec E\cdot d\vec r \end{align*}

The first method is similar to how we calculated the electric field for distributed charges in Chapter 15.1, but with the simplification that we only need to sum scalars instead of vectors. The second method was already introduced in this chapter.

17.5Electric field and potential at the surface of a conductor

Conducting materials are always equipotential surfaces (or volumes) if charges are not moving inside the conductor. This is because the electric field inside a conductor is always zero and thus, a charge moving through a conductor experiences no electric force and its electrical potential energy will be constant. Similarly, because the electric field must always be perpendicular to an equipotential, electric field lines are always perpendicular to the surface of a conductor (in electrostatics).

If we consider a conducting sphere of radius RR and charge +Q+Q, the electric field at the surface of the sphere is given by:

E=kQR2E=k\frac{Q}{R^2}

as we found in Chapter 16.1. If we define electric potential to be zero at infinity, then the electric potential at the surface of the sphere is given by:

V=kQRV=k\frac{Q}{R}

In particular, the electric field at the surface of the sphere is related to the electric potential at its surface by:

E=VRE=\frac{V}{R}

Thus, if two spheres are at the same electric potential, the one with the smaller radius will have a stronger electric field at its surface.

Because a conducting sphere is symmetric, the charges will distribute themselves symmetrically around the whole outer surface of the sphere. The charge per unit area, σ, at the surface of the sphere is thus given by:

σ=Q4πR2\begin{align*} \sigma &= \frac{Q}{4\pi R^2} \end{align*}

The charge density can be related to the electric field at the surface of the sphere:

E=kQR2=k4πR2σR2=4πσk=σϵ0\begin{align*} E&=k\frac{Q}{R^2}=k\frac{4\pi R^2\sigma}{R^2}=4\pi\sigma k=\frac{\sigma}{\epsilon_0} \end{align*}

where in the last equality, we used kk with ϵ0\epsilon_0 and confirmed the general result from Section 16.4, where we determined the electric field near a conductor with surface charge σ.

Consider a sphere of radius R1R_1 that carries total charge, +Q+Q. A neutral second, smaller, conducting sphere, of radius R2R_2, is then connected to the first sphere, using a conducting wire, as in Figure 11.

Two conducting spheres are connected by a conducting wire. The charge $Q$ that was originally on the larger sphere distributes itself onto the two spheres.

Figure 11:Two conducting spheres are connected by a conducting wire. The charge QQ that was originally on the larger sphere distributes itself onto the two spheres.

Because the charges on the large sphere can move around freely, some of them will move to the smaller sphere. Very quickly, the charges will stop moving and the spheres of radius R1R_1 and R2R_2 will end up carrying charges Q1Q_1 and Q2Q_2, respectively (we assume that the wire is small enough that negligible amounts of charge are distributed on the wire). Since the two conducting spheres are connected by a conductor, they form an equipotential, and are thus at the same voltage, VV, relative to infinity. Since the two spheres are at the same electric potential, the electric field at the surface of each sphere are related:

E1=VR1E2=VR2E2E1=R1R2E2=E1R1R2\begin{align*} E_1&=\frac{V}{R_1}\\ E_2&=\frac{V}{R_2}\\ \therefore \frac{E_2}{E_1}&=\frac{R_1}{R_2}\\ \therefore E_2&=E_1\frac{R_1}{R_2} \end{align*}

and the electric field at the surface of the smaller sphere, E2E_2, is stronger since R2<R1R_2<R_1. We can also compare the surface charge densities on the two spheres:

E1=σ1ϵ0E2=σ2ϵ0σ2σ1=E2E1=R1R2σ2=σ1R1R2\begin{align*} E_1&=\frac{\sigma_1}{\epsilon_0}\\ E_2&=\frac{\sigma_2}{\epsilon_0}\\ \therefore \frac{\sigma_2}{\sigma_1}&=\frac{E_2}{E_1}=\frac{R_1}{R_2}\\ \therefore \sigma_2&=\sigma_1 \frac{R_1}{R_2} \end{align*}

and we find that the charge density is higher on the smaller sphere. Thus, there are more charges per unit area on the smaller sphere than the bigger sphere.

We can generalize this model to describe charges on any charged conducting object. If charges are deposited on a conducting object that is not a sphere, as in Figure 12, they will not distribute themselves uniformly. Instead, there will be a higher charge density (charges per unit area), near parts of the object that have a small radius of curvature, just as the charge density was higher on the smaller sphere described above. As a consequence of the higher concentration of charges near the “pointier” parts of the object, the electric field at the surface will be the strongest in those regions.

On an uneven conductor, charges will accumulate on the sharper points, where the radius of curvature is the smallest.

Figure 12:On an uneven conductor, charges will accumulate on the sharper points, where the radius of curvature is the smallest.

In air, if the electric field exceeds a magnitude of approximately 3×106V/m3\times 10^{6} {\rm V/m}, the air is said to “electrically break down”. The strong electric field can remove electrons from atoms in the air, ionizing the air in a chain reaction and making it conductive. Thus, if the electric field at a point on the surface of a conductor is very strong, the air near that point will break down, and charges will leave the conductor, through the air, to find a location with lower electric potential energy (usually the ground). Electric breakdown is what we experience as a spark (or lightning, on a larger scale), and is usually a discrete (and potentially dramatic) event. Corona discharge is another mechanism whereby the strong electric field can make the air conductive, but in this case, charges leak into the air more gradually, unlike in the case of electrical break down. Charges leaking into air through Corona discharge will emit a faint blueish light (the “Corona”) as well as an audible hissing sound.

Objects that are designed to hold a high electric potential (for example the electrodes on high voltage lines) are usually made very carefully so that they have a very smooth surface and no sharp edges. This reduces the risk of breakdown or Corona discharge at the surface which would result in a loss of charge.

Contrary to popular belief, lightning rods are not designed to attract lightening. Instead, lightning rods are designed to be conductors with a very sharp point, so that Corona discharge can occur at their tip. This allows charges to slowly leak off from the Earth into the cloud through Corona discharge, thereby reducing the potential difference between the cloud and Earth so that a lightning strike (electrical breakdown) does not occur. When a lightning strike does occur, it will hit the lightning rod, since the electric field at the top of the rod is high and that is the most likely point for the air to break down; but, that is not the goal of the lightning rod!

17.6Capacitors

Capacitors are common electronic devices that are used to store electric charge for a variety of applications. A capacitor is usually constructed with two conducting plates (called “terminals” or “electrodes”) separated by either air or an insulating material.

Two examples of capacitors. The left panel shows a "parallel plate" capacitor, and the right panel shows a cylindrically shaped capacitor obtained by "rolling up" a parallel plate capacitor.

Figure 13:Two examples of capacitors. The left panel shows a “parallel plate” capacitor, and the right panel shows a cylindrically shaped capacitor obtained by “rolling up” a parallel plate capacitor.

Figure 13 shows two examples of capacitors. The left panel shows a “parallel plate” capacitor, consisting of two conducting plates separated by air or an insulator. The plates are conducting in order for one to be able to easily add and remove charge to the plates. The plates always hold equal and opposite charges. The right panel shows a more practical implementation of a capacitor that could be used in a circuit, which is simply made by “rolling up” a parallel plate capacitor (with an insulator instead of air separating the plates so that they do not touch).

17.6.1Capacitance

As long as the quantities of charge involved are not too large, it has been observed that the amount of charge, QQ, that can be stored on a capacitor[43], is linearly proportional to the potential difference, ΔV\Delta V, between the two plates:

QΔVQ\propto \Delta V
Q=CΔV\boxed{Q=C\Delta V}

The constant of proportionality, CC, between charge and potential difference across the capacitor (usually called voltage across the capacitor) is called “capacitance”, and has S.I. units of “Farads” (F{\rm F}). The capacitance of a particular capacitor is a measure of how much charge it can hold at given voltage and depends on the geometry of the capacitor as well as the material between the terminals. If too much charge is placed on a capacitor, the material between the two plates will break down, and a spark will usually damage the capacitor as well as discharge it.

We can easily calculate the capacitance of a parallel plate capacitor. We model the capacitor as being made of two conducting plates, each with area, AA, separated by a distance, LL, and holding charge with magnitude, QQ. The surface charge density on one of the plates, σ, is just given by:

σ=QA\sigma =\frac{Q}{A}

In Example 17.3, we found an expression for the potential difference between two parallel plates:

ΔV=σϵ0L=(LAϵ0)Q\begin{align*} \Delta V &= \frac{\sigma}{\epsilon_0}L=\left(\frac{L}{A\epsilon_0}\right)Q \end{align*}

Comparing with, Q=CΔVQ=C\Delta V, the capacitance of the parallel plate capacitor is found to be:

C=ϵ0ALC=\epsilon_0\frac{A}{L}

It makes sense that the capacitance, the amount of charge that can be stored at a given voltage, increases if the plates have a larger area (more space for charges), and decreases if the plates are further apart . %todo: ask (smaller electric field).

Capacitors are used in many touch screens. For example, these might be made of glass (an insulator), with a thin metal coating that one touches to interact with the screen (one of the plates). As you touch the metal plate, you effectively change the capacitance of the screen, which can be sensed and modelled to determine the location of your finger(s). Modern touch screens have many capacitors built directly into the screen, and function based on this principle.

17.6.2Dielectric materials

In practice, capacitors always have an insulating material between the two plates. The material is chosen to have a higher breakdown voltage than air, so that more charges can be stored before a breakdown occurs. It has also been experimentally observed that the capacitance increases with certain materials, so called “dielectric materials”. A dielectric material has a “dielectric constant”, KK, defined to be the amount by which the capacitance increases:

C=KC0C=KC_0

where CC is the capacitance with the material in place, and C0C_0 is the capacitance when there is a vacuum between the plates (the dielectric constant of air is very close to 1). Often, rather than the dielectric constant, one uses the “permittivity”, ε, of a material:

ϵ=Kϵ0\epsilon=K\epsilon_0

based on the permittivity of free space, ϵ0\epsilon_0. The capacitance of a parallel plate capacitor, with a material that has permittivity, ε, is thus given by:

C=Kϵ0AL=ϵALC=K\epsilon_0\frac{A}{L}=\epsilon\frac{A}{L}

Dielectric materials are made of molecules that can be polarized (such as water), namely molecules that have a non-zero electric dipole moment. When the dielectric material is placed between the plates, the dipoles inside the material align themselves with the electric field from the plates. This leads to a second electric field, from the dipoles, in the opposite direction of the field from the plates, thus reducing the total electric field between the plates. This, in turn, allows more charges to be held on the plate for a given voltage. This is illustrated in Figure 14

A dielectric material is placed between the two plates of a capacitor. The electric dipoles in the dielectric have random orientations when the plates are neutral (left panel). When the plates are charged (right panel), the dipoles align themselves with the field from the plates, allowing more charge to be on the plates at a given potential difference.

Figure 14:A dielectric material is placed between the two plates of a capacitor. The electric dipoles in the dielectric have random orientations when the plates are neutral (left panel). When the plates are charged (right panel), the dipoles align themselves with the field from the plates, allowing more charge to be on the plates at a given potential difference.

Note that, in a dielectric material with permittivity ε, Gauss’s Law is modified to read:

EdA=Qencϵ\oint \vec E\cdot d\vec A=\frac{Q^{enc}}{\epsilon}

where the permittivity of free space, ϵ0\epsilon_0, is simply replaced with the permittivity of the material, ε.

17.6.3Energy stored in a capacitor

The charges stored on a capacitor have electric potential energy: if one were to place a conductor between the plates, charges would immediately conduct from one plate to the other and gain kinetic energy. We can model the amount of energy stored on the capacitor by considering how much work it takes to place the charges on the capacitor.

Imagine that both plates on the capacitor start with a charge of magnitude qq. We then remove an infinitesimal negative charge, with magnitude dqdq, from the positive plate and place it on the negative plate. This required work, since we had to pull this negative charge away from the positive plate. If the potential difference across the plates is ΔV\Delta V, then we had to do an amount of work given by:

dW=ΔVdqdW = \Delta Vdq

since the charge dqdq has now gained potential energy, ΔVdq\Delta Vdq. The potential difference is dependent on the (constant) capacitance of the capacitor, and the amount of charge, qq, already stored on the plates:

q=CΔVΔV=qC\begin{align*} q &= C\Delta V\\ \therefore \Delta V&=\frac{q}{C} \end{align*}

In order to determine the work required to transfer a total amount of charge, QQ, we sum the work in transferring each infinitesimal charge, dqdq:

W=dW=0QΔVdq=0QqCdq=12Q2CW=\int dW=\int_0^Q \Delta Vdq=\int_0^Q \frac{q}{C}dq=\frac{1}{2}\frac{Q^2}{C}

Thus, the total potential energy that is stored on a capacitor is given by:

U=12Q2C=12C(ΔV)2=12QΔVU = \frac{1}{2}\frac{Q^2}{C} = \frac{1}{2}C(\Delta V)^2=\frac{1}{2}Q\Delta V

where we made use of Q=CΔVQ=C\Delta V to show the formula with different choices of variables. In either case, the amount of energy that is stored increases with the amount of charge, the capacitance, and the voltage across the capacitor. Capacitors are useful because this energy can be released quickly, as in the bright flash of light required for flash photography.

17.7Summary

The electric force is conservative, so we can define a potential energy function, U(r)U(\vec r). The potential energy function for a point charge, qq, at position r\vec r, relative to a point charge, QQ, is given by:

U(r)=kQrq+CU(\vec r) = \frac{kQ}{r}q + C

where CC is an arbitrary constant, since only differences in potential energy are physically meaningful (as they correspond to work). Note that the sign of the electrical potential energy will depend on the relative sign of qq and QQ. If a collection of charges are held together, the total electrical potential energy that is stored is called “electrostatic potential energy”.

Similarly to how the electric field, E(r)\vec E(\vec r), corresponds to electric force per unit charge, “electric potential”, V(r)V(\vec r), corresponds to electric potential energy per unit charge. The electric potential at a position, r\vec r, relative to a point charge, QQ, is given by:

V(r)=U(r)q=kQr+CV(\vec r) =\frac{U(\vec r)}{q}= \frac{kQ}{r} + C'

and also depends on an arbitrary constant, CC', since only differences in electric potential will lead to differences in potential energy. The value of the electric potential, VV, at some position in space, r\vec r, allows us to determine the electric potential energy, UU, at that position for any charge, qq:

U=qVU = qV

This is analogous to determining the force on a charge, qq, when we know the electric field at some point in space:

F=qE\vec F = q \vec E

Differences in electric potential are called “voltages”, and the S.I. unit of potential is called the “volt” (V). In S.I. units, the electric field is often expressed in units of volts per metre (V/m).

When a particle with charge qq changes position such that the corresponding change in electric potential is ΔV\Delta V, the particle’s potential energy will change by:

ΔU=qΔV\Delta U = q\Delta V

In particular, a negative charge will experience a decrease in potential energy when the electric potential increases, whereas a positive charge will experience an increase in potential energy when the electric potential increases. This reflects the fact that the electric force associated with the electric potential will act in opposite directions on a positive and a negative charge.

In order to describe the energies of particles interacting with electric forces, it is more convenient to use the “electron volt” instead of the Joule. An electron volt is defined as the energy that is gained by a charge with a magnitude ee (the magnitude of the charge of the electron) when accelerated through a potential difference of ΔV=1V\Delta V=1 {\rm V}:

1eV=(e)(1V)=1.6×1019J\begin{align*} 1 {\rm eV}&=(e)(1 {\rm V})=1.6\times 10^{-19} {\rm J} \end{align*}

The electric potential function can be determined in two different ways:

  1. By modelling the charge distribution as the sum of infinitesimal point charges, dqdq, and adding together the electric potentials, dVdV, from all charges, dqdq. This requires that one choose 0V0 {\rm V} to be located at infinity, so that the dVdV are all relative to the same point.
  2. By calculating the electric field (either as a integral or from Gauss’ Law), and using:
ΔV=V(rB)V(rA)=ABEdr\begin{align*} \Delta V &=V(\vec r_B)-V(\vec r_A)=-\int_A^B \vec E\cdot d\vec r \end{align*}

It is worth noting that one needs to be very careful with the signs when using the above integral. In particular note that one takes the negative of the integral, from AA to BB, to determine the potential at BB minus the potential at AA.

Similarly, one can determine the value of the electric field, E(r)=E(x,y,z)\vec E(\vec r)=\vec E(x,y,z), from the electric potential, V(r)=V(x,y,z)V(\vec r)=V(x,y,z):

E(x,y,z)=V=Vxx^Vyy^Vzz^\vec E(x,y,z) = -\nabla V =-\frac{\partial V}{\partial x}\hat x-\frac{\partial V}{\partial y}\hat y-\frac{\partial V}{\partial z}\hat z

where, V\nabla V, is the gradient of the electric potential.

The electric potential can be visualized in a number of ways. The most common is to draw contours of constant electric potential, akin to the contours on geographical maps that are used to show regions of constant altitude (i.e. constant gravitational potential energy).

Regions of constant electric potential are called “equipotentials”, and can be lines, surfaces or volumes. Equipotentials are always perpendicular to the electric field. In electrostatics (when charges are not moving), the electric field in a conductor must be zero, so that a conductor always forms an equipotential, and the electric field at the surface of a conductor is always perpendicular to the surface.

When charges are placed on a conductor, they will spread out along the outer surface of the conductor. The surface density of charges will be the highest where the conductor has the smallest radius of curvature (e.g. at a sharp point). Consequently, the electric field at the surface of a charged conductor is highest near sharp points.

Capacitors are devices that are used to store charge. They are usually made using two conducting plates (“terminals” or “electrodes”) that hold equal and opposite charge, QQ, at a fixed potential difference, ΔV\Delta V , between the electrodes. The amount of charge that is stored on the capacitor is observed to be proportional to the potential difference between the electrodes:

Q=CΔVQ=C\Delta V

where the constant of proportionality, CC, is called the “capacitance” of the capacitor. The S.I. unit of capacitance is the “Farad” (F). The capacitance of a capacitor depends on its geometry (e.g. its size) and the materials that it is placed between the electrodes.

Usually, one places a dielectric material between the two electrodes in order to increase the capacitance, and to reduce the risk of breakdown. If that material has a “dielectric constant”, KK, then the capacitance is given by:

C=KC0C=KC_0

where, C0C_0, corresponds to the capacitance if there were vacuum between the electrodes. The dielectric constant of air is very close to 1, so that a capacitor in air is very similar to a capacitor in vacuum. A dielectric material is one that is made of molecules that can be polarized under the presence of an electric field; that is, the molecules have an electric dipole moment. When the molecules in a material are polarized, this reduces the total electric field in the material, which increases the capacitance of the capacitor. Inside a dielectric material, we can define the “permittivity”, ε, as:

ϵ=Kϵ0\epsilon=K\epsilon_0

where ϵ0\epsilon_0 is the permittivity of free space. Within a dielectric material, Gauss’ Law is modified to:

EdA=Qencϵ\oint \vec E \cdot d\vec A=\frac{Q^{enc}}{\epsilon}

Since charges are held at a fixed potential difference on a capacitor, capacitors are a way of storing electric potential energy. The amount of electric potential energy stored in a capacitor with capacitance, CC, when the capacitor has a potential difference, ΔV\Delta V, across its electrodes, is given by:

U=12Q2C=12C(ΔV)2=12QΔVU = \frac{1}{2}\frac{Q^2}{C} = \frac{1}{2}C(\Delta V)^2=\frac{1}{2}Q\Delta V

17.8Thinking about the material

17.9Sample problems and solutions

17.9.1Problems

17.9.2Solutions